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Scientists have achieved the first real-time visualization of how 'excited-state aromaticity' emerges within just hundreds of femtoseconds and then triggers a molecule to change from bent to ...
Saito explains that selenium’s large size allows overlapping σ orbitals from the six atoms to create aromaticity. The phenylselenyl groups donate electron density to the benzene to make ...
Aromaticity, a concept usually used to explain the striking stability and unusual reactivity of certain carbon-based molecules, could inspire the design of new catalysts with novel uses, KAUST ...
First experimental evidence of 3D aromaticity in stacked antiaromatic compounds Date: December 15, 2016 Source: Nagoya University Summary: Researchers found that antiaromatic planar norcorrole ...
Physical Chemistry Pnictogen Ring Boasts Aromaticity Inorganic Chemistry: Anion made solely from phosphorus and nitrogen is stabilized by electron delocalization by Bethany Halford ...
Scientists have achieved the first real-time visualization of how "excited-state aromaticity" emerges within just hundreds of femtoseconds and then triggers a molecule to change from ...
The concept of aromaticity underpins much of modern organic chemistry, describing the unusual stability and reactivity of cyclic molecules whose π-electrons are delocalised over a planar framework.
Double Aromaticity and Anti-aromaticity in Small Carbon Rings. Sonsoles Martín-Santamaría and Henry S. Rzepa* Department of Chemistry, Imperial College of Science, Technology and Medicine, London, SW7 ...
Table S1. Calculated (B3LYP/6-31G(d) ) Geometries and transition normal modes for the electrocyclic ring openings 1-4 ...
Theoretical chemistry, molecular properties, ring currents, aromaticity, fullerenes, molecular electronic devices, symmetry and discrete mathematics in chemistry.